помогите с переведом - вопрос №1736815

We have illustrated how strong electronic coupling between the transition metal centers and the organic conduct-ing polymer backbone facilitates electronic charge transport. The intimate involvement of the transition metal centers in the conductivity pathway provides an approach to chemoresistive chemical sensors. For example, the redox potential of a coordinatively unsaturated transition metal will be highly sensitive to small molecule or ion binding. Analyte induced changes in the metal’s redox potential will affect the degree of overlap with the conducting polymer thereby creating a measurable response in conductivity. The matching of the metal center’s and organic polymer’s redox potentials can be either increased or decreased depending on whether the binding event shifts the redox potential of the metal center into a state of better overlap with the polymer backbone or worse overlap.

декабрь 1, 2015 г.